Product ID:22-404, CITGARD 500 MOTOR OIL SAE 40
MSDS Date:04/17/1989
FSC:9150
NIIN:00N019699
MSDS Number: BNNNM

CITGO PETROLEUM CORP

TULSA, OK 74102
US

Emergency Phone: 318-491-6215

Info Phone: 918-495-5933

Cage: 7X110

CITGO PETROLEUM CORP

3758 TULSA, OK 74102 US

Telephone: 918-495-5933

Cage: 7X110

AROUND SPILL AREA. REPORTS SPILLS AS REQUIRED

RTECS: 9999999ZZ

STATE & LOC LAWS & REGS. CONSIDER CHARACTS

RTECS: 9999999ZZ

FLAMMABLE/EXPLO VAPS. CONSULT APPROP FED,

RTECS: 9999999ZZ

RECLAIMING, RECYCLING OR DISPOSING OF EMPTY CNTNRS

RTECS: 9999999ZZ

MANDATED STANDARDS AS EVALUATED BY DESIGNATED

RTECS: 9999999ZZ

DETERGENT INHIBITOR (CONTAINS ZINC DIALKYLDITHIOPHOSPHATE)

Fraction By Weight: 10-15%

ZINC DIALKYLDITHIOPHOSPHATE

CAS: 68649-42-3

Fraction By Weight: <4%

MINERAL OIL, PETROLEUM DISTILLATES, SOLV-REFINED (SEVERE)

CAS: 64741-89-5

RTECS: PY8041501

OSHA PEL N/K

ACGIH TLV: N/K

MINERAL OIL, PETROLEUM DISTILLATES, HYDROTREATED (SEVERE)

CAS: 64742-54-7

RTECS: PY8035501

OSHA PEL N/K

ACGIH TLV: N/K

MINERAL OIL, PETROLEUM DISTILLATES, HYDROTREATED (SEVERE)

CAS: 64742-55-8

RTECS: PY8036501

OSHA PEL N/K

ACGIH TLV: N/K

SOLVENT REFINED HYDROTREATED RESIDUAL OIL; (HYDROTREATED

CAS: 64742-57-0

OSHA PEL N/K

ACGIH TLV: N/K

SEVERELY HYDROTREATED HYDROCARBON OIL; (HYDROTREATED

CAS: 72623-87-1

OSHA PEL N/K

ACGIH TLV: N/K

HIGHLY REFINED BASE OIL; (HYDROTREATED HIGH-VISCOSITY

CAS: 72623-85-9

OSHA PEL N/K

ACGIH TLV: N/K

MINERAL OIL; (HYDROTREATED BRIGHT STOCK LUBRICATING OIL)

CAS: 72623-83-7

OSHA PEL N/K

ACGIH TLV: N/K

MINERAL OIL, PETROLEUM DISTILLATE, CATALYTIC DEWAXED, HEAVY

CAS: 64742-70-7

RTECS: PY8045500

OSHA PEL N/K

ACGIH TLV: N/K

HYDROTREATMENT); (CATALYTIC DEWAXED PARAFFINIC OIL)

RTECS: 9999999ZZ

DETERGENT INHIBITOR (CONTAINS INGREDIENT 17)

Fraction By Weight: <20%

OSHA PEL N/K

ACGIH TLV: N/K

PHOSPHORODITHOIC ACID, O-O-D1 C1-14-ALKYL ESTERS, ZINC

CAS: 68649-42-3

Fraction By Weight: <20%

OSHA PEL N/K

ACGIH TLV: N/K

VI IMPROVER

Fraction By Weight: 0-15%

OSHA PEL N/K

ACGIH TLV: N/K

POUR POINT DEPRESSANT

Fraction By Weight: 0-1%

OSHA PEL N/K

ACGIH TLV: N/K

INJECTION REQUIRES PROMPT SURGICAL DEBRIDEMENT. IF

RTECS: 9999999ZZ

REFINED PETROLEUM OILS (CONTAINS INGREDIENTS 2, 3 & 4).

RTECS: 9999999ZZ

Fraction By Weight: 85-95%

OSHA PEL 5 MG/M3

ACGIH TLV: 5 MG/M3;10 PPM STEL

MINERAL OIL, PETROLEUM DISTILLATES, SOLVENT-DEWAXED HEAVY

CAS: 64742-65-0

RTECS: PY8038500

MINERAL OIL, PETROLEUM DISTILLATES, SOLVENT-REFINED HEAVY

CAS: 64741-88-4

RTECS: PY8040500

SOLVENT REFINED RESIDUM

CAS: 64742-01-4

LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:PRACTICALLY NON-TOXIC. ACUTE:
INHAL:LOW RISK AT AMBIENT TEMPS. MISTS OR FUMES MAY CAUSE
DIZZINESS, HEADACHE, NAUSEA, RESPIRATORY IRRITATION OR CHEMICAL
PNEUM. SKIN:TRANSIENT, SLIGHT IRRITATION. EYE:PR ACTICALLY
NON-IRRITANT. INGEST:LOW TOX.IF LESS THAN ONE OUNCE IS INGESTED,
MATL MAY PASS THRU SYSTEM (EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZ: WITHOUT HARM. ON INGESTION OF LARGE
QTYS SLIGHT GI DISCOMFORT, DIARRHEA, AND HEADACHE MAY OCCUR.
INJECTION:SUBCUTANEOUS OR INTRAMUSCULAR INJECTION MAY CAUSE IRRIT,
ERYTHEMA, EDEMA. CHRONIC: DERMAL, PROLONGED AND REPEATED
EXPOSUREMAY CAUSE DRYING OF THE SKIN.
Medical Cond Aggravated by Exposure:NONE

First Aid:INHAL:REMOVE FROM EXPOS TO INCIDENTAL FUMES & PROVIDE RESP
SUPPORT IF NECESSARY. SKIN:WASH WITH SOAP & WATER. EYES:FLUSH WITH
LRG VOLUMES OF WATER FOR AT LEAST 15 MIN. INGEST:INDUCE VOMIT &
CALL MD. N OTE TO MD:FOLLOWING INGEST, AT A SAYBOLT VISCOSITY OF
800 @ 100F, THE RISK OF ASPIR INTO LUNGS IS REDUCED. FOR QTYS >1
OZ, EMESIS/LAVAGE MAY BE CONSIDERED. SUBCUTANEOUS INJECTION REQ
PROMPT(SUPP DATA)

Flash Point Method:COC
Flash Point:468F,242C
Extinguishing Media:CO*2, DRY CHEMICAL, FOAM, WATER FOG.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA & FULL
PROTECTIVE EQUIPMENT .
Unusual Fire/Explosion Hazard:WATER MAY CAUSE FROTHING.

Spill Release Procedures:REMOVE SOURCES OF HEAT/IGNIT.PROVIDE ADEQ
VENT.SM SPILLS:TAKE UP W/NONCOMBUST ABSORB SUCH AS FULLERS
EARTH/SAND.PLACE INTO CNTNRS FOR LATER DISP.LRG SPILLS:CONTAIN
SPILL IN EARTHEN DIKES FOR LATER REC OVERY.CONTROL IGNIT SOURCES
AROUND SPILL(SUPPDATA)
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:KEEP CNTNRS TIGHTLY CLSD & AWAY FROM
HEAT & FLAME. AVOID PRLNGD SKIN CONT W/USED MOTOR OILS. DO NOT
INHALE MISTS OR FUMES.
Other Precautions:CONTINUOUS CONTACT WITH USED OIL HAS CAUSED SKIN
CANCER IN LAB ANIMALS. AFTER DRAINING OIL, WASH SKIN THORO WITH
SOAP & WATER. EMPTY CNTNRS MAY CONTAIN PRODUCT RESIDUE WHICH COULD
INCLUDE FLAMMABLE OR EXPLOSIVE VAPORS.

Respiratory Protection:IF HIGH VAPOR CONCENTRATION IS EXPECTED, USE
NIOSH/MSHA APPROVED RESPIRATOR FOR ORGANIC VAPORS.
Ventilation:USE IN WELL VENT AREA.IN CONFINED SPACES, MECH VENT MAY BE
REQ TO KEEP LEVELS OF CERTAIN COMPONENTS Protective Gloves:OIL IMPERVIOUS GLOVES.
Eye Protection:CHEMICAL WORKERS GOGGLES .
Other Protective Equipment:WEAR BODY-COVERING WORK CLOTHES TO AVOID
PROLONGED OR REPEATED EXPOSURE. LAUNDER SOILED WORK CLOTHES BEFORE
REUSE.
Work Hygienic Practices:WASH EXPOSED SKIN THOROUGHLY WITH SOAP AND
WATER. REMOVE SOILED CLOTHING. LAUNDER BEFORE REUSE.
Supplemental Safety and Health
VAP PRESS: <1X10-3 @ 25C. FIRST AID PROC:SURGICAL DEBRIDEMENT. IF NOT
FAMILIAR WITH TECHNIQUE, SEEK SKILLED ADVICE. SPILL PROC:AREA.
REPORT SPILLS AS REQUIRED TO APPROPRIATE AUTHORITIES.

HCC:V6
Boiling Pt:B.P. Text:720F,382C
Vapor Pres:SUPP DATA
Vapor Density:>1
Spec Gravity:0.89 (H*2O=1)
Evaporation Rate & Reference:<1 (BUTYL ACETATE = 1)
Solubility in Water:NEGLIGIBLE
Appearance and Odor:AMBER LIQUID, MILD ODOR.
Percent Volatiles by Volume:NEGL

Stability Indicator/Materials to Avoid:YES
STRONG OXIDANTS, STRONG ACIDS, CAUSTICS.
Stability Condition to Avoid:NONE
Hazardous Decomposition Products:THERMAL: CO*2, (CO UNDER INCOMPLETE
COMBUSTION), TRACES OF OXIDES OF S, ZN, P AND CA.

Waste Disposal Methods:IT IS THE RESPONSIBILITY OF THE USER TO
DETERMINE IF MATL IS A HAZ WASTE AT TIME OF DISP. CHECK BEFORE
DISPOSING TO BE SURE YOU ARE IN COMPLIANCE W/ALL APPLIC FEDERAL, ST
& LOCAL LAWS & REGS. TREAT US ED OIL ACCORDING TO CURRENT RULES &
REGS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.